SQL Server 2019

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DECLARE @Emp TABLE
    (
        [EId] INT IDENTITY(1, 1)
      , [FN]  NVARCHAR(50)
      , [LN]  NVARCHAR(50)
    ) ;
DECLARE @EmpPhCont TABLE
    (
        [EId]       INT
      , [PhType]    VARCHAR(10)
      , [PhNum]     VARCHAR(16)
      , [PhExt]     VARCHAR(10)
      , [IsMain]    BIT
      , [CreatedOn] DATETIME
    ) ;

INSERT INTO @Emp
VALUES
    ( N'Emp1', N'Emp1' )
  , ( N'Emp2', N'Emp2' )
  , ( N'Emp3', N'Emp3' )
  , ( N'Emp4', N'Emp4' )
  , ( N'Emp5', N'Emp5' )
  , ( N'Emp6', N'Emp5' ) ;

INSERT INTO @EmpPhCont
VALUES
    ( 1, 'Home', '111111111', NULL, 0, '2020-01-01 00:00:01' )
  , ( 1, 'Mobile', '222222222', NULL, 1, '2020-01-01 00:00:02' )
  , ( 1, 'Work', '333333333', NULL, 0, '2020-01-01 00:00:03' )

, ( 2, 'Work', '444444444', '567', 1, '2020-01-01 00:00:04' )
  , ( 2, 'Mobile', '555555555', NULL, 0, '2020-01-01 00:00:05' )
  , ( 2, 'Mobile', '454545454', NULL, 0, '2020-01-01 00:00:06' )

, ( 3, 'Home', '777777777', NULL, 0, '2020-01-01 00:00:07' )
  , ( 3, 'Mobile', '888888888', NULL, 1, '2020-01-01 00:00:08' )
  , ( 3, 'Mobile', '12121212', NULL, 0, '2020-01-01 00:00:09' )

, ( 4, 'Work', '101010101', '111', 1, '2020-01-01 00:00:10' )
  , ( 4, 'Work', '101010102', '232', 0, '2020-01-01 00:00:11' )

, ( 5, 'Work', '545454545', '456', 0, '2020-01-01 00:00:10' )
  , ( 5, 'Work', '456456456', NULL, 1, '2020-01-01 00:00:11' );
  
with cte as (
  select *,
    row_number() over (partition by [EId], [PhType] order by [IsMain] desc, [CreatedOn] desc) rn
  from @EmpPhCont
)
select e.[EId],
  max(case when c.[PhType] = 'Home' then c.[PhNum] end) HomeNum,
  max(case when c.[PhType] = 'Mobile' then c.[PhNum] end) MobileNum,
  max(case when c.[PhType] = 'Work' then c.[PhNum] end) WorkNum,
  max(case when c.[PhType] = 'Work' then c.[PhExt] end) WorkNumExt,
  max(case when c.[IsMain] = 1 then c.[PhType] end) MainPhType 
from @Emp e left join cte c
on c.[EId] = e.[EId] and c.rn = 1
group by e.[EId]

EId	HomeNum	MobileNum	WorkNum	WorkNumExt	MainPhType
1	111111111	222222222	333333333	null	Mobile
2	null	454545454	444444444	567	Work
3	777777777	888888888	null	null	Mobile
4	null	null	101010101	111	Work
5	null	null	456456456	null	Work
6	null	null	null	null	null

Warning: Null value is eliminated by an aggregate or other SET operation.