MySQL 8.0

By using db<>fiddle, you agree to license everything you submit by Creative Commons CC0.

CREATE TABLE shifts (
    id int NOT NULL,
    unique_id varchar(255) NOT NULL,
    start_date DATETIME NOT NULL,
    end_date DATETIME NOT NULL,
    PRIMARY KEY (id)
);

CREATE TABLE appointments (
    id int NOT NULL,
    unique_id varchar(255) NOT NULL,
    start_date DATETIME NOT NULL,
    end_date DATETIME NOT NULL,
    shift_id int NOT NULL,
    PRIMARY KEY (id),
    FOREIGN KEY (shift_id) REFERENCES shifts(id)
);

INSERT INTO `shifts` (`id`, `unique_id`, `start_date`, `end_date`)
VALUES
	('4596', '614fc0c5dab2485bba8cbbd9eb98aa53', '2022-02-28 10:00:00', '2022-03-15 19:00:00');

INSERT INTO `appointments` (`id`, `unique_id`, `start_date`, `end_date`, `shift_id`)
VALUES
	(18352, 'accdc12943954ee2bd69ad116c2fef3d', '2022-02-28 18:15:00', '2022-02-28 19:00:00', 4596),
	(18351, '6a0d56ad43894b60b4f8a289fbbfff73', '2022-02-28 17:30:00', '2022-02-28 18:15:00', 4596),
	(18545, '4a49c054e59e4514ae2a521b55a7715c', '2022-02-28 16:50:00', '2022-02-28 17:15:00', 4596),
	(18622, '02ca48b35ca3462f9030bcb97ea1dbab', '2022-02-28 16:30:00', '2022-02-28 16:50:00', 4596),
	(18544, 'd27bc7ba34a74f078966ebe1567d3181', '2022-02-28 16:00:00', '2022-02-28 16:30:00', 4596),
	(18685, '4057b87c089b463188a26bc45d85388a', '2022-02-28 15:00:00', '2022-02-28 15:10:00', 4596),
	(18462, '3270929ae6e546fb824e6d3219917b8e', '2022-02-28 14:30:00', '2022-02-28 16:00:00', 4596),
	(18235, 'deac969701ae47f0a78696f12c267475', '2022-02-28 14:00:00', '2022-02-28 14:30:00', 4596),
	(18540, 'e16af8a053594e8b8340ede302398a22', '2022-02-28 13:30:00', '2022-02-28 14:00:00', 4596),
	(18537, 'e1946add03cd412da357b58c93d58c6e', '2022-02-28 12:30:00', '2022-02-28 13:15:00', 4596),
	(18355, 'ec570f9365bb4ad68c7b5ab3b7d9aeea', '2022-02-28 12:00:00', '2022-02-28 12:30:00', 4596),
	(18523, 'aff5abe6e8f84a64ace3277d3cd6dbd1', '2022-02-28 11:00:00', '2022-02-28 12:00:00', 4596),
	(18517, '124baaa1aeab421cb288f2b7c7abe89b', '2022-02-28 10:30:00', '2022-02-28 11:00:00', 4596),
	(18382, '1371e41a7cf342bfa279a8b120cc5f43', '2022-02-28 10:00:00', '2022-02-28 10:30:00', 4596);

Available_from	Available_to
2022-02-28 13:16:00	2022-02-28 13:29:00
2022-02-28 17:16:00	2022-02-28 17:29:00