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db<>fiddle
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CREATE TABLE MyTable
(
P_Id int,
amount varchar(50)
)

insert into MyTable values(1,2340.65);
insert into MyTable values(2,4568);
insert into MyTable values(3,10000);
insert into MyTable values(4,2340.40);
4 rows affected
SELECT * FROM MyTable
ORDER BY CAST(amount AS Numeric(10,2)) DESC

P_Id amount
3 10000
2 4568
1 2340.65
4 2340.40